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Phase-field Modeling of Phase Changes and Mechanical Stresses in Electrode Particles of Secondary Batteries

By: Material type: ArticleArticleLanguage: English Publication details: Karlsruhe KIT Scientific Publishing 2021Description: 1 electronic resource (224 p.)ISBN:
  • KSP/1000100537
  • 9783731510024
Subject(s): Online resources: Summary: Most storage materials exhibit phase changes, which cause stresses and, thus, lead to damage of the electrode particles. In this work, a phase-field model for the cathode material NaxFePO4 of Na-ion batteries is studied to understand phase changes and stress evolution. Furthermore, we study the particle size and SOC dependent miscibility gap of the nanoscale insertion materials. Finally, we introduce the nonlocal species concentration theory, and show how the nonlocality influences the results.
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Most storage materials exhibit phase changes, which cause stresses and, thus, lead to damage of the electrode particles. In this work, a phase-field model for the cathode material NaxFePO4 of Na-ion batteries is studied to understand phase changes and stress evolution. Furthermore, we study the particle size and SOC dependent miscibility gap of the nanoscale insertion materials. Finally, we introduce the nonlocal species concentration theory, and show how the nonlocality influences the results.

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