Electrochemical SPM study of 2D phase and 3D phase formation of Zn at the ionic liquid / Au(111) interface [online] (Record no. 79090)

MARC details
000 -LEADER
fixed length control field 02176naaaa2200289uu 4500
001 - CONTROL NUMBER
control field https://directory.doabooks.org/handle/20.500.12854/46134
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20220220093740.0
020 ## - INTERNATIONAL STANDARD BOOK NUMBER
International Standard Book Number KSP/1132004
020 ## - INTERNATIONAL STANDARD BOOK NUMBER
International Standard Book Number 3937300090
024 7# - OTHER STANDARD IDENTIFIER
Standard number or code 10.5445/KSP/1132004
Terms of availability doi
041 0# - LANGUAGE CODE
Language code of text/sound track or separate title English
042 ## - AUTHENTICATION CODE
Authentication code dc
100 1# - MAIN ENTRY--PERSONAL NAME
Personal name Dogel, Jana
Relationship auth
245 10 - TITLE STATEMENT
Title Electrochemical SPM study of 2D phase and 3D phase formation of Zn at the ionic liquid / Au(111) interface [online]
260 ## - PUBLICATION, DISTRIBUTION, ETC.
Name of publisher, distributor, etc. KIT Scientific Publishing
Date of publication, distribution, etc. 2004
506 0# - RESTRICTIONS ON ACCESS NOTE
Terms governing access Open Access
Source of term star
Standardized terminology for access restriction Unrestricted online access
520 ## - SUMMARY, ETC.
Summary, etc. Zn electrodeposition in the under- (UPD) and overpotential (OPD) ranges by means of in-situ Scanning Tunneling Microscopy (STM) was examined, supported by in-situ cyclic voltammetry and chronoamperometrie. The underpotential deposition of Zn follows a layer-by-layer growth. For the first time the formation of three successive Zn monolayers has been observed in the UPD range. It has been shown, that the UPD of Zn is complicated due to surface alloying. The same growth mechanism extends from the UPD into OPD range until Al bulk deposition sets in. The UPD of Al at 100 mV vs. Zn/Zn(II) is marked by Moiré pattern formation. For the first time in this system the effective tunneling barrier f has been measured by STS. A first insight into the 2D phase formation of electrodeposited Zn at the electrolyte / electrode interface was obtained from STM images at various times and potentials. Before a coherent layer is formed wormlike structures are observed characteristic of spinodal decomposition. This implies a first order phase transition, which has been resolved here for the first time for 2D electrodeposition.
540 ## - TERMS GOVERNING USE AND REPRODUCTION NOTE
Terms governing use and reproduction All rights reserved
-- http://oapen.org/content/about-rights
546 ## - LANGUAGE NOTE
Language note English
653 ## - INDEX TERM--UNCONTROLLED
Uncontrolled term electrochemistry
653 ## - INDEX TERM--UNCONTROLLED
Uncontrolled term spinodal decomposition
653 ## - INDEX TERM--UNCONTROLLED
Uncontrolled term STM
653 ## - INDEX TERM--UNCONTROLLED
Uncontrolled term zinc
653 ## - INDEX TERM--UNCONTROLLED
Uncontrolled term layer growth
856 40 - ELECTRONIC LOCATION AND ACCESS
Host name www.oapen.org
Uniform Resource Identifier <a href="https://www.ksp.kit.edu/3937300090">https://www.ksp.kit.edu/3937300090</a>
Access status 0
Public note DOAB: download the publication
856 40 - ELECTRONIC LOCATION AND ACCESS
Host name www.oapen.org
Uniform Resource Identifier <a href="https://directory.doabooks.org/handle/20.500.12854/46134">https://directory.doabooks.org/handle/20.500.12854/46134</a>
Access status 0
Public note DOAB: description of the publication

No items available.