TY - GEN AU - Zhang,Tao TI - Phase-field Modeling of Phase Changes and Mechanical Stresses in Electrode Particles of Secondary Batteries SN - KSP/1000100537 PY - 2021/// CY - Karlsruhe PB - KIT Scientific Publishing KW - Mechanical engineering & materials KW - bicssc KW - Phasenfeldansatz KW - Phasentrennung KW - Nichtlokalität KW - Endliche Verformungselastizität KW - Sekundärbatterien KW - Phase-field approach KW - Phase segregation KW - Nonlocality KW - Finite deformation elasticity KW - Secondary batteries N1 - Open Access N2 - Most storage materials exhibit phase changes, which cause stresses and, thus, lead to damage of the electrode particles. In this work, a phase-field model for the cathode material NaxFePO4 of Na-ion batteries is studied to understand phase changes and stress evolution. Furthermore, we study the particle size and SOC dependent miscibility gap of the nanoscale insertion materials. Finally, we introduce the nonlocal species concentration theory, and show how the nonlocality influences the results UR - https://library.oapen.org/bitstream/20.500.12657/50992/1/9783731510024.pdf UR - https://directory.doabooks.org/handle/20.500.12854/72269 ER -