Canac, Yves <br/><br/>
Carbon Ligands : From Fundamental Aspects to Applications 

 - Basel, Switzerland  MDPI - Multidisciplinary Digital Publishing Institute  2021 
 - 1 electronic resource (311 p.) 
<br/><br/> Open Access 
<br/><br/> Homogeneous catalysis owes its success, in large part, to the development of a wide range of ligands with well-defined electronic and steric properties, which have thus made it possible to adjust the behavior of many organometallic complexes. However, ligands used in catalysis have long been centered on elements of group 15, and it is only more recently that carbon ligands have proved to be valuable alternatives with the emergence of cyclic diaminocarbenes (NHC).This Special Issue aims to provide a contemporary overview of the advances in carbon ligand chemistry from fundamental aspects to applications. 
<br/><br/><br/>Creative Commons 
<br/><br/><br/>English 
<br/><br/><label>ISBN: </label>books978-3-0365-1349-2 9783036513508 9783036513492 
<br/><br/><label>Standard No.: </label>10.3390/books978-3-0365-1349-2  doi 
<br/><br/><label>Subjects--Topical Terms: </label><br/>Research & information: general
<br/><br/><label>Subjects--Index Terms: </label>carbenes ylides DFT calculations electronic structure catalysis ligands structure–activity relationship NHC nanoparticle calixarene palladium catalyst Suzuki-Miyaura reaction amino-acids water carbon ligand amide negative charge phosphonium ylide oxide pincer metathesis ruthenium nitro catalysts NHC ligands olefins selenonium ylides selenonium salts chirality stereogenic selenium atom asymmetric synthesis optical resolution reactivity malaria Plasmodium falciparum gold NHC-ligands hybrid molecules drug resistance N-heterocyclic carbene platinum metal complexes 195Pt NMR N-heterocyclic carbenes imidazole spectroscopy X-ray mercury(II) complex T-shaped carbodiphosphorane phosphorus ylides pincer ligands coordination chemistry Cu(I) complex photoluminescence titanium hafnium copolymerization of epoxide with CO2 density functional theory natural bond orbitals aromaticity ion pairs alkali metals tropylidenyl ions cyclooctatetraene ions rhodium electron paramagnetic resonance (EPR) spectroscopy density functional theory (DFT) electrochemistry carbone complexes carbido complexes transition metal complexes chemical bonding pincer ligand macrocycle lithium potassium intramolecular C-H activation dehydrogenation carbone ligand germylene coordination ylide n/a