| 000 | 02593naaaa2200289uu 4500 | ||
|---|---|---|---|
| 001 | https://directory.doabooks.org/handle/20.500.12854/70460 | ||
| 020 | _aintechopen.80549 | ||
| 024 | 7 |
_a10.5772/intechopen.80549 _cdoi |
|
| 041 | 0 | _aEnglish | |
| 042 | _adc | ||
| 072 | 7 |
_aPN _2bicssc |
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| 100 | 1 |
_aTojo, C. _4auth |
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| 700 | 1 |
_aBuceta, David _4auth |
|
| 700 | 1 |
_aArturo López-Quintela, M. _4auth |
|
| 245 | 1 | 0 | _aChapter Microemulsions as Nanoreactors to Obtain Bimetallic Nanoparticles |
| 260 |
_bInTechOpen _c2019 |
||
| 506 | 0 |
_aOpen Access _2star _fUnrestricted online access |
|
| 520 | _aMicroemulsions are frequently used as nanoreactors for the synthesis of bimetallic nanoparticles. The ability to manipulate the metal distribution in bimetallic nanoparticles is essential for optimizing applications, and it requires a deeper understanding of how compartmentalization of reaction medium affects nanoparticle synthesis. A simulation model was developed to predict the atomic structure of bimetallic nanoparticles prepared via microemulsion in terms of metals employed and microemulsion composition. The model was successfully proved by comparing theoretical and experimental Au/Pt STEM profiles. On this basis, the model becomes a strong tool to further enhance our knowledge of the complex mechanisms governing reactions in microemulsions and its impact on final nanostructures. The purpose of this study is to perform a comprehensive kinetic analysis of coreduction of different couple of metals in the light of the interplay between three kinetic parameters: intermicellar exchange rate, chemical reduction rates of the two metals, and reactants concentration. The particular combination of these factors determines the reaction rate of each metal, which in turn determines the final metal arrangement. | ||
| 540 |
_aCreative Commons _fhttps://creativecommons.org/licenses/by/3.0/ _2cc _4https://creativecommons.org/licenses/by/3.0/ |
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| 546 | _aEnglish | ||
| 650 | 7 |
_aChemistry _2bicssc |
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| 653 | _abimetallic nanoparticles, microemulsions, reduction rate, intermicellar exchange rate, nanocatalysts | ||
| 773 | 1 | 0 |
_0OAPEN Library ID: ONIX_20210602_10.5772/intechopen.80549_412 _7nnaa |
| 856 | 4 | 0 |
_awww.oapen.org _uhttps://library.oapen.org/bitstream/20.500.12657/49298/1/63269.pdf _70 _zDOAB: download the publication |
| 856 | 4 | 0 |
_awww.oapen.org _uhttps://library.oapen.org/bitstream/20.500.12657/49298/1/63269.pdf _70 _zDOAB: download the publication |
| 856 | 4 | 0 |
_awww.oapen.org _uhttps://directory.doabooks.org/handle/20.500.12854/70460 _70 _zDOAB: description of the publication |
| 999 |
_c42820 _d42820 |
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