000			02176naaaa2200289uu 4500
001			https://directory.doabooks.org/handle/20.500.12854/46134
005			20220220093740.0
020			_aKSP/1132004
020			_a3937300090
024	7		_a10.5445/KSP/1132004 _cdoi
041	0		_aEnglish
042			_adc
100	1		_aDogel, Jana _4auth
245	1	0	_aElectrochemical SPM study of 2D phase and 3D phase formation of Zn at the ionic liquid / Au(111) interface [online]
260			_bKIT Scientific Publishing _c2004
506	0		_aOpen Access _2star _fUnrestricted online access
520			_aZn electrodeposition in the under- (UPD) and overpotential (OPD) ranges by means of in-situ Scanning Tunneling Microscopy (STM) was examined, supported by in-situ cyclic voltammetry and chronoamperometrie. The underpotential deposition of Zn follows a layer-by-layer growth. For the first time the formation of three successive Zn monolayers has been observed in the UPD range. It has been shown, that the UPD of Zn is complicated due to surface alloying. The same growth mechanism extends from the UPD into OPD range until Al bulk deposition sets in. The UPD of Al at 100 mV vs. Zn/Zn(II) is marked by Moiré pattern formation. For the first time in this system the effective tunneling barrier f has been measured by STS. A first insight into the 2D phase formation of electrodeposited Zn at the electrolyte / electrode interface was obtained from STM images at various times and potentials. Before a coherent layer is formed wormlike structures are observed characteristic of spinodal decomposition. This implies a first order phase transition, which has been resolved here for the first time for 2D electrodeposition.
540			_aAll rights reserved _4http://oapen.org/content/about-rights
546			_aEnglish
653			_aelectrochemistry
653			_aspinodal decomposition
653			_aSTM
653			_azinc
653			_alayer growth
856	4	0	_awww.oapen.org _uhttps://www.ksp.kit.edu/3937300090 _70 _zDOAB: download the publication
856	4	0	_awww.oapen.org _uhttps://directory.doabooks.org/handle/20.500.12854/46134 _70 _zDOAB: description of the publication
999			_c79090 _d79090