000 03567naaaa2200385uu 4500
001 https://directory.doabooks.org/handle/20.500.12854/73729
005 20220220100533.0
020 _a978-2-88963-577-1
020 _a9782889635771
024 7 _a10.3389/978-2-88963-577-1
_cdoi
041 0 _aEnglish
042 _adc
072 7 _aPD
_2bicssc
100 1 _aCognet, Patrick
_4edt
700 1 _aKheireddine Aroua, Mohamed
_4edt
700 1 _aCognet, Patrick
_4oth
700 1 _aKheireddine Aroua, Mohamed
_4oth
245 1 0 _aFrom Glycerol to Value-Added Products
260 _bFrontiers Media SA
_c2020
300 _a1 electronic resource (171 p.)
506 0 _aOpen Access
_2star
_fUnrestricted online access
520 _aIn a context where the role of biofuels will continue to grow, it is necessary to take into account the current state of their various manufacturing processes and to anticipate the expansion of the market. Thus, current biodiesel production processes generate a significant amount of glycerol as a by-product (about 100 kg per ton of processed vegetable oil). An explosion of the biodiesel market must integrate the valorization of glycerol whose current market of distribution (cosmetics, drugs, polymers, etc.) is not guaranteed such an expansion. This valuation will contribute effectively to the profitability and sustainability of the processes from which it derives. Glycerol physicochemical and toxicological properties give it the potential to be used as solvent, biolubricant, dispersant, and surfactant, among others. It is also widely used in the food industry as a preservative and sweetener. Beyond these applications, glycerol can also be used as a raw material for a wide range of chemicals. Glycerol is a highly functionalized molecule with specific physico-chemical properties, which can be used in different reactions as a reactant or a building block. For example, glycerol can be used as a starting material for antibiotic production, biosurfactants, organic acid production (lactic, propionic, succinic, citric acid, glyoxylic acid, glyoxalic acid, amino acids, etc.), alcohols (propanediols), glycerol esters, acrolein production, etc. These products can be obtained either through chemical reactions such as acetalization, dehydration, glycerolysis, esterification, etherification, aqueous phase reforming, oxidation, carboxylation, electrochemical routes, or through enzymatic reactions. However, it must be kept in mind that the development of industrial processes relies on the use of crude glycerol from biodiesel production. For that purpose, robust processes involving impurities-insensitive catalysts or pre-purification have to be developed. Finally, the separation of the chemical products obtained after glycerol conversion is also a key step toward the development of viable glycerol-based processes.
540 _aCreative Commons
_fhttps://creativecommons.org/licenses/by/4.0/
_2cc
_4https://creativecommons.org/licenses/by/4.0/
546 _aEnglish
650 7 _aScience: general issues
_2bicssc
653 _aglycerol
653 _agreen chemistry
653 _acatalysis
653 _aprocess
653 _aactivation
653 _aadded value bio-based products
653 _aelectrochemical conversions
856 4 0 _awww.oapen.org
_uhttps://www.frontiersin.org/research-topics/8342/from-glycerol-to-value-added-products
_70
_zDOAB: download the publication
856 4 0 _awww.oapen.org
_uhttps://directory.doabooks.org/handle/20.500.12854/73729
_70
_zDOAB: description of the publication
999 _c80294
_d80294