000 04654naaaa2201021uu 4500
001 https://directory.doabooks.org/handle/20.500.12854/68533
005 20220220102004.0
020 _abooks978-3-0365-0431-5
020 _a9783036504308
020 _a9783036504315
024 7 _a10.3390/books978-3-0365-0431-5
_cdoi
041 0 _aEnglish
042 _adc
072 7 _aGP
_2bicssc
100 1 _aShenderovich, Ilya
_4edt
700 1 _aShenderovich, Ilya
_4oth
245 1 0 _aGulliver in the Country of Lilliput : An Interplay of Noncovalent Interactions
260 _aBasel, Switzerland
_bMDPI - Multidisciplinary Digital Publishing Institute
_c2021
300 _a1 electronic resource (216 p.)
506 0 _aOpen Access
_2star
_fUnrestricted online access
520 _aNoncovalent interactions are the bridge between ideal gas abstraction and the real world. For a long time, they were covered by two terms: van der Waals interactions and hydrogen bonding. Both experimental and quantum chemical studies have contributed to our understanding of the nature of these interactions. In the last decade, great progress has been made in identifying, quantifying, and visualizing noncovalent interactions. New types of interactions have been classified—their energetic and spatial properties have been tabulated. In the past, most studies were limited to analyzing the single strongest interaction in the molecular system under consideration, which is responsible for the most important structural properties of the system. Despite this limitation, such an approach often results in satisfactory approximations of experimental data. However, this requires knowledge of the structure of the molecular system and the absence of other competing interactions. The current challenge is to go beyond this limitation. This Special Issue collects ideas on how to study the interplay of noncovalent interactions in complex molecular systems including the effects of cooperation and anti-cooperation, solvation, reaction field, steric hindrance, intermolecular dynamics, and other weak but numerous impacts on molecular conformation, chemical reactivity, and condensed matter structure.
540 _aCreative Commons
_fhttps://creativecommons.org/licenses/by/4.0/
_2cc
_4https://creativecommons.org/licenses/by/4.0/
546 _aEnglish
650 7 _aResearch & information: general
_2bicssc
653 _asolvent effect
653 _ahydrogen bond
653 _aNMR
653 _acondensed matter
653 _apolarizable continuum model
653 _areaction field
653 _aexternal electric field
653 _aproton transfer
653 _ahalogen bond
653 _aphosphine oxide
653 _a31P NMR spectroscopy
653 _aIR spectroscopy
653 _anon-covalent interactions
653 _aspectral correlations
653 _aReaction mechanism
653 _afirst-principle calculation
653 _aBader charge analysis
653 _aactivation energy
653 _atransition state structure
653 _aconventional and non-conventional H-bonds
653 _aempirical Grimme corrections
653 _alattice energy of organic salts
653 _acomputation of low-frequency Raman spectra
653 _aconfinement
653 _asolid-state NMR
653 _amolecular dynamics
653 _ainterfaces and surfaces
653 _asubstituent effect
653 _aaromaticity
653 _aadenine
653 _aLewis acid–Lewis base interactions
653 _atetrel bond
653 _apnicogen bond
653 _atriel bond
653 _aelectron charge shifts
653 _aproton dynamics
653 _acarboxyl group
653 _aCPMD
653 _aDFT
653 _aIINS
653 _aIR
653 _aRaman
653 _acrystal engineering
653 _ahalogen bonding
653 _aazo dyes
653 _aQTAIM
653 _adispersion
653 _aketone–alcohol complexes
653 _adensity functional theory
653 _ahydrogen bonds
653 _amolecular recognition
653 _avibrational spectroscopy
653 _agas phase
653 _abenchmark
653 _apinacolone
653 _adeuteration
653 _aheavy drugs
653 _ahistamine receptor
653 _ahydrogen bonding
653 _areceptor activation
653 _an/a
856 4 0 _awww.oapen.org
_uhttps://mdpi.com/books/pdfview/book/3554
_70
_zDOAB: download the publication
856 4 0 _awww.oapen.org
_uhttps://directory.doabooks.org/handle/20.500.12854/68533
_70
_zDOAB: description of the publication
999 _c80923
_d80923